International Journal of Advanced and Applied Sciences

Int. j. adv. appl. sci.

EISSN: 2313-3724

Print ISSN: 2313-626X

Volume 4, Issue 5  (May 2017), Pages:  35-40


Title: Physics of ZnO/SiO2 electrolyte semi-conductive thermal electric generator

Author(s):  Ataur Rahman *, Kyaw Myo Aung, Khalid Saifullah, Mizanur Rahman

Affiliation(s):

Department of Mechanical Engineering, Faculty of Engineering, International Islamic University Malaysia, 50728 Kuala Lumpur, Malaysia

https://doi.org/10.21833/ijaas.2017.05.006

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Abstract:

Thermoelectric generator generates electrical power from heat based on the temperature gradient. The total energy (fuel) supplied to the engine, approximately 30 to 40% is converted into useful mechanical work, whereas the remaining is expelled to the environment as heat through exhaust gases and cooling systems, resulting in serious greenhouse gas (GHG) emission. The technologies reported on waste heat recovery from exhaust gas of internal combustion engines (ICE) are thermo electric generators (TEG) with finned type, Rankine cycle (RC) and Turbocharger by the different researchers. The deficiency and acclimatization of existing TEG emphasis this study to develop a nanomaterial zinc oxide (ZnO)/Silicon di-oxide (SiO2) electrolyte based semi-conductive thermal electric generator (TEG) to generate electricity from the IC engine exhaust heat. This technology produces electricity from the exhaust heat due to the thermal motion, carrier drift and carrier diffusion. The ZnO/SiO2 simulated result based on the 60% of exhaust heat of IC engine shows that its electrical energy generation is about 80% more than conventional TEG for the exhaust temperature of 500°C due to its higher thermal and electric conductivity and higher surface area both in radially and longitudinally. The ZnO/SiO2 electrolyte semi-conducive technology develops 524W to 1600W at engine speed 1000 to 5000 rpm, which could contribute to reduce the 10-12% of engine total fuel consumption and improve emission level by 20%. 

© 2017 The Authors. Published by IASE.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Keywords: ZiO/SiO2 electrolytic TEG, Electrical power generation, Carrier drift and diffusion, IC engine exhaust heat, Emission reduction

Article History: Received 13 December 2016, Received in revised form 12 February 2017, Accepted 23 February 2017

Digital Object Identifier: 

https://doi.org/10.21833/ijaas.2017.05.006

Citation:

Rahman A, Aung KM, Saifullah K, and Rahman M (2017). Physics of ZnO/SiO2 electrolyte semi-conductive thermal electric generator. International Journal of Advanced and Applied Sciences, 4(5): 35-40

http://www.science-gate.com/IJAAS/V4I5/Rahman.html


References:

Anedda R, Cannas C, Musinu A, Pinna G, Piccaluga G, and Casu M (2008). A two-stage citric acid–sol/gel synthesis of ZnO/SiO2 nanocomposites: study of precursors and final products. Journal of Nanoparticle Research, 10(1): 107-120.
https://doi.org/10.1007/s11051-007-9235-5
Cannas C, Musinu A, Peddis D, and Piccaluga G (2006). Synthesis and characterization of CoFe2O4 nanoparticles dispersed in a silica matrix by a Sol− Gel autocombustion method. Chemistry of Materials, 18(16): 3835-3842.
https://doi.org/10.1021/cm060650n
Chain K, Huang JH, Duster J, Ko PK, and Hu C (1997). A MOSFET electron mobility model of wide temperature range (77-400 K) for IC simulation. Semiconductor Science and Technology, 12(4): 355–358.
https://doi.org/10.1088/0268-1242/12/4/002
Chelikowsky JR and Schlüter M (1977). Electron states in α-quartz: A self-consistent pseudopotential calculation. Physical Review B, 15(8): 4020-4029
https://doi.org/10.1103/PhysRevB.15.4020
Conklin JC and Szybist JP (2010). A highly efficient six-stroke internal combustion engine cycle with water injection for in-cylinder exhaust heat recovery. Energy, 35(4): 1658-1664.
https://doi.org/10.1016/j.energy.2009.12.012
Dolz V, Novella R, García A, and Sánchez J (2012). HD Diesel engine equipped with a bottoming Rankine cycle as a waste heat recovery system. Part 1: Study and analysis of the waste heat energy. Applied Thermal Engineering, 36: 269-278.
https://doi.org/10.1016/j.applthermaleng.2011.10.025
Hatazawa M, Sugita H, Ogawa T, and Seo Y (2004). Performance of a thermoacoustic sound wave generator driven with waste heat of automobile gasoline engine. Transactions of the Japan Society of Mechanical Engineers, 70(689B):292–299.
https://doi.org/10.1299/kikaib.70.292
Homm G and Klar PJ (2011). Thermoelectric materials–Compromising between high efficiency and materials abundance. Physica Status Solidi (RRL)-Rapid Research Letters, 5(9): 324-331.
Jeon DS and Burk DE (1989). MOSFET electron inversion layer mobilities-a physically based semi-empirical model for a wide temperature range. IEEE Transactions on Electron Devices, 36(8): 1456-1463.
https://doi.org/10.1109/16.30959
Mang A and Reimann K, and Rübenacke ST (1995). Band gaps, crystal-field splitting, spin-orbit coupling, and exciton binding energies in ZnO under hydrostatic pressure. Solid State Communications, 94(4): 251-254.
https://doi.org/10.1016/0038-1098(95)00054-2
Rahman A, Abdul Razak F, Hawlader MNA, and Rashid M (2013). Nonlinear modeling and simulation of waste energy harvesting system for hybrid engine: Fuzzy logic approach. Journal of Renewable and Sustainable Energy, 5(3): 1-13.
https://doi.org/10.1063/1.4802946
Rahman A, Razzak F, Afroz R, Mohiuddin AKM and Hawlader MNA (2015). Power generation from waste of IC engines. Renewable and Sustainable Energy Reviews, 51: 382-395.
https://doi.org/10.1016/j.rser.2015.05.077
Reitz RD (2012). Reciprocating internal combustion engines. Engine research center, University of Wisconsin-Madison. Available online at: https://www.researchgate.net/profile/Rolf_Reitz/publication/265804679_Reciprocating_Internal_Combustion_Engines/links/5630d3d808ae0530378cddc5.pdf
Sabnis AG and Clemens JT (1979). Characterization of the electron mobility in the inverted< 100> Si surface. In the International Electron Devices Meeting, IEEE, Washington, USA: 18-21. https://doi.org/10.1109/IEDM.1979.189528
Saidur R, Rahim NA, and Hasanuzzaman M (2010). A review on compressed-air energy use and energy savings. Renewable and Sustainable Energy Reviews, 14(4): 1135-1153.
https://doi.org/10.1016/j.rser.2009.11.013
Stabler F (2002). Automotive applications of high efficiency thermoelectrics. In the DARPA/ONR/DOE High Efficiency Thermoelectric Workshop, San Diego, USA: 1-26.
Stobart RK, Wijewardane A and Allen C (2010). The potential for thermo-electric devices in passenger vehicle applications. In the SAE 2010 World Congress & Exhibition, Detroit, USA.
https://doi.org/10.4271/2010-01-0833
Varshni YP (1967). Temperature dependence of the energy gap in semiconductors. Physica, 34(1): 149-154.
https://doi.org/10.1016/0031-8914(67)90062-6
Yang J (2005). Potential applications of thermoelectric waste heat recovery in the automotive industry. In the 24th International Conference on Thermoelectrics (ICT 2005), IEEE, Clemson, USA: 170-174. 
https://doi.org/10.1109/ict.2005.1519911
Yu C and Chau KT (2009) Thermoelectric automotive waste heat energy recovery using maximum power point tracking. Energy Conversion and Management, 50(6): 1506-1512.
https://doi.org/10.1016/j.enconman.2009.02.015