International Journal of Advanced and Applied Sciences

Int. j. adv. appl. sci.

EISSN: 2313-3724

Print ISSN: 2313-626X

Volume 3, Issue 10  (October 2016), Pages:  14-19


Title: Conductivity studies of graphene oxide on biopolymer electrolyte

Author(s):  Syakirah Shahrudin 1, Azizah Hanom Ahmad 1, 2, *

Affiliation(s):

1Faculty of Applied Sciences, Universiti Teknologi MARA (UiTM), 40450 Shah Alam, Selangor, Malaysia
2Institute of Science, Universiti Teknologi Mara (UITM), 40450 Shah Alam, Selangor, Malaysia

https://doi.org/10.21833/ijaas.2016.10.003

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Abstract:

In this research, biopolymer electrolyte has been prepared by doping cornstarch with sodium iodide (NaI) using solution casting method. The incorporation of 25% NaI resulted in maximum conductivity of the electrolyte at 1.46 x 10-4 S cm-1. The enhancement of the electrical conductivity to 2.61 x 10-3 S cm-1 was achieved with further addition of graphene oxide (GO). The effect of GO on the electrolyte system were investigated by deploying electrical impedance spectroscopy (EIS) measurement at temperature of 298K-373K.  Electrical conductivity as function of temperature have been investigated and revealed that the conductivity decreases as temperature increase. Dielectric studies were performed in order to study the ion mobility in the electrolyte system. 

© 2016 The Authors. Published by IASE.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Keywords: Biopolymer electrolyte, Cornstarch/NaI, GO

Article History: Received 8 August 2016, Received in revised form 21 September 2016, Accepted 7 October 2016

Digital Object Identifier: https://doi.org/10.21833/ijaas.2016.10.003

Citation:

Shahrudin Sand Ahmad AH (2016). Conductivity studies of graphene oxide on biopolymer electrolyte. International Journal of Advanced and Applied Sciences, 3(10): 14-19

http://www.science-gate.com/IJAAS/V3I10/Shahrudin.html


References:

Balog R, Jørgensen B, Nilsson L, Andersen M, Rienks E, Bianchi M and Sljivancanin Z (2010). Bandgap opening in graphene induced by patterned hydrogen adsorption. Nature Materials, 9(4): 315-319.
http://dx.doi.org/10.1038/nmat2710
PMid:20228819
Bhargav PB, Mohan VM, Sharma AK and Rao VN (2007). Structural and electrical studies of sodium iodide doped poly (vinyl alcohol) polymer electrolyte films for their application in electrochemical cells. Ionics, 13(3): 173-178.
http://dx.doi.org/10.1007/s11581-007-0102-2
Das TK and Prusty S (2013). Graphene-based polymer composites and their applications. Polymer-Plastics Technology and Engineering, 52(4): 319-331.
http://dx.doi.org/10.1080/03602559.2012.751410
Deshmukh K and Joshi GM (2015). Embedded capacitor applications of graphene oxide reinforced poly (3, 4-ethylenedioxythiophene)-tetramethacrylate (PEDOT-TMA) composites. Journal of Materials Science: Materials in Electronics, 26(8): 5896-5909.
http://dx.doi.org/10.1007/s10854-015-3159-0
Dikin DA, Stankovich S, Zimney EJ, Piner RD, Dommett GH, Evmenenko G and Ruoff RS (2007). Preparation and characterization of graphene oxide paper. Nature, 448(7152): 457-460.
http://dx.doi.org/10.1038/nature06016
PMid:17653188
Diwan P, Harms S, Raetzke K and Chandra A (2012). Polymer electrolyte-graphene composites: Conductivity peaks and reasons thereof. Solid State Ionics, 217: 13-18.
http://dx.doi.org/10.1002/pc.22309
Dzulkurnain NA, Ahmad A and Mohamed NS (2015). P (MMA-EMA) random copolymer electrolytes incorporating sodium iodide for potential application in a dye-sensitized solar cell. Polymers, 7(2):266-280.
http://dx.doi.org/10.3390/polym7020266
Hu F, Li W, Zhang J and Meng W (2014). Effect of graphene oxide as a dopant on the electrochemical performance of graphene oxide/polyaniline composite. Journal of Materials Science and Technology, 30(4): 321-327.
http://dx.doi.org/10.1016/j.jmst.2013.10.009
Huang X, Zhi C, Jiang P, Golberg D, Bando Y and Tanaka T (2012). Temperature-dependent electrical property transition of graphene oxide paper. Nanotechnology, 23(45): 455705, 10 pages.
http://dx.doi.org/10.1088/0957-4484/23/45/455705
PMid:23085763
Joshi GM and Deshmukh K (2016). Study of conjugated polymer/graphene oxide nanocomposites as flexible dielectric medium. Journal of Materials Science: Materials in Electronics, 27(4): 3397-3409.
http://dx.doi.org/10.1007/s10854-015-4172-z
Khan MS and Shakoor A (2015). Ionic conductance, thermal and morphological behavior of PEO-graphene oxide-salts composites. Journal of Chemistry, 2015: Article ID 695930, 6 pages. 
http://dx.doi.org/10.1155/2015/695930
Kumar KS, Pittala S, Sanyadanam S and Paik P (2015). A new single/few-layered graphene oxide with a high dielectric constant of 10 6: contribution of defects and functional groups. Rsc Advances, 5(19): 14768-14779.
http://dx.doi.org/10.1039/C4RA10800K
Kumar M, Tiwari T and Srivastava N (2012). Electrical transport behaviour of bio-polymer electrolyte system: Potato starch+ ammonium iodide. Carbohydrate Polymers, 88(1): 54-60.
http://dx.doi.org/10.1016/j.carbpol.2011.11.059
Latif I, Alwan TB and Al-Dujaili AH (2012). Low frequency dielectric study of PAPA-PVA-GR Nano composites. Nanoscience and Nanotechnology, 2(6): 190-200.
http://dx.doi.org/10.5923/j.nn.20120206.07
Ning W, Xingxiang Z, Haihui L and Jianping W (2009). N, N-dimethylacetamide/lithium chloride plasticized starch as solid biopolymer electrolytes. Carbohydrate polymers, 77(3): 607-611.
http://dx.doi.org/10.1016/j.carbpol.2009.02.002
Quan H, Zhang BQ, Zhao Q, Yuen RK and Li RK (2009). Facile preparation and thermal degradation studies of graphite Nano platelets (GNPs) filled thermoplastic polyurethane (TPU) Nano composites. Composites Part A: Applied Science and Manufacturing, 40(9): 1506-1513.
http://dx.doi.org/10.1016/j.compositesa.2009.06.012
Shanti R (2011). Investigation on the effects of ionic liquid and ionic mixture in biodegradable polymer electrolytes. M.Sc. Thesis, Faculty of Engineering and Science, Universiti Tunku Abdul Rahman.
Shukur MF, Ithnin R and Kadir MFZ (2014). Electrical properties of proton conducting solid biopolymer electrolytes based on starch–chitosan blend. Ionics, 20(7): 977-999.
http://dx.doi.org/10.1007/s11581-013-1033-8
Syzdek J, Armand M, Marcinek M, Zalewska A, Żukowska G and Wieczorek W (2010). Detailed studies on the fillers modification and their influence on composite, poly (oxyethylene)-based polymeric electrolytes. Electrochimica Acta, 55(4): 1314-1322.
http://dx.doi.org/10.1016/j.electacta.2009.04.025
Yu L, Zhang Y, Tong W, Shang J, Lv F, Chu PK and Guo W (2012). Hierarchical composites of conductivity controllable polyaniline layers on the exfoliated graphite for dielectric application. Composites Part A: Applied Science and Manufacturing, 43(11): 2039-2045.
http://dx.doi.org/10.1016/j.compositesa.2012.06.001
Yusof YM, Shukur MF, Illias HA and Kadir MFZ (2014). Conductivity and electrical properties of corn starch–chitosan blend biopolymer electrolyte incorporated with ammonium iodide. Physica Scripta, 89(3): 035701, http:// stacks.iop.org/1402-4896/89/i=3/a=035701
http://dx.doi.org/10.1088/0031-8949/89/03/035701